资源描述
物理化学学报( luli Huaxue Xuebao)
1330
Acta Phys.- Chin.Sim.2016,32(6),1330-1346
une
Review
doi:10.3866/PKU.WHXB201603073
www.wh
su.edu. cn
Cu2ZnSn(S,Se)薄膜太阳电池研究进展
张雪'韩洋1柴双志1胡南滔1杨志'耿
(上海交通大学电子信息与电气工程学院,上海20040:3安阳师范学院物理与电气工程も院,河南安阳453
摘要:CdTe和cu(n,Ga)(S,Se)( CIGSSE)光吸收材料在新型化合物半导、A电池研元、片据着主导地
位。尽管cdTe和C?GS太阳电池拥有较高的转换效率和先进的技术,但是
些问题,如所用材料
中的元素地壳丰度低或有毒,这阻碍了其未来的大规模应用。近年
2Z
Se( CZTSSE)薄膜
太阳电池使用的元素地壳含量丰富且环境友好,逐渐成为了研究的热点
Se光吸收材料被认为能够取
代CdTe和CIGS成为下一代光伏技术的潜力材料。基于此,本文将
争、TSSe材料的结构、性质和
制备方法。重点闻述 CZTSSE7材料的组装技术和沉积方法的发展利优势,/基千空的沉积方法和基于溶液
的沉积方法,简述其优缺点。此外,木文对 CZTSSE组装利CzTS
昂制方法的最新研究进展也进行
了总结。最后,对 CZT Sse光伏技术的一些限制因素进行
e薄膜电池未来的研究前景进
行了展望。
关鍵词: Cu2znsn(s,Se);薄膜:太阳电池;制方
中图分类号:O646
Advances in Cu2 Zn/n(
Thin Film Solar Cells
ZHANG Xue
HAN/ang
lang-zhi'
HU Nan-tao
YANG Zh
NGH
NE Hao
School of Electronic information and E
Engine ing, Shanghai Jiao Tong University, Shanghai 200240 P R. China
College of Physics and Electri <, eering
Normal University, Anyang 455000, Henan Province, P R China
Abstract: Cdte and Cu(n Ga) (CIGSSE )light absorber materials have dominated the research field
of compound semicon r solar cew Despite the high power conversion efficiencies and technological
advances of Cdte andcig photovoltaic technologies, certain issues, like rare earth constituent elements or
toxic elements limi ir ut ups led applications. In recent years Cu Sn(, Se)(CZTSSE)thin film solar
cells have become researck
lots, drawing increased interest With earth-abundant and environmental
benign constituent elements ZTSSE light absorber materials are widely regarded as the next-generation
photovoltaic/ hnology that can replace Cdte and CIGS as a promising candidate for terawatt-level power
output. In
ew, the synthesis, structure, and properties of Ztsse materials will be discussed. This review
will primily d onst e the developments and recent advances of different fabrication techniques and
deposition meth s, ch as vacuum-based and solution-based deposition methods, covering their advantages
and isa anag ecent developments in ZTSSE fabricaion methods and CZTSSE nanocrystal preparation
oaches will a so e re w Fill m limi o on e photovoltaic technology will be analyzed
Directions for improvement will be sugested, helping scientists o make future developments in this field
Key vo s: Cu: Znsn(, Se)]; Thin flm; Solar cell; Preparation method; Research progress
Received: January 18, 2016; Revised: March 7, 2016; Published on Web: March 7, 2016
CorrespondingauthorsWEIHao,Email:haowei@sjtu.edu.cn;tel/fax:+86-21-34206398.GENGHui-juan,Email:ghjhou(@126.com
YANGZhi,Email:zhiyang@situ.edu.cn
The project was supported by the National Natural Science Foundation of China(61376003)
国家自然科学基金(61376003)资助项目
O Editorial office of Acta Physico-chimica Sinica
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